不銹鋼的(de)爐(lu)中釬焊一般是在某種保(bao)護性氣(qi)氛下或(huo)真空中進(jin)行,保(bao)護氣(qi)氛有(you)氫(qing)氣(qi)、分解氨和氬氣(qi)。
干燥的氫氣或分解氨常用做爐中釬焊不銹鋼時的還原性保護氣氛,它們可還原不銹鋼表面的氧化膜,并保護不銹鋼表面在釬焊時不再氧化。一般要求氫氣或分解氨的露點低于-40℃,但也要考慮保護氣體的露點要與釬焊溫度及母材的成分相適應。釬焊溫度越低、不銹鋼表面氧化膜越穩定,要求氫氣露點越低,見圖3-4。使用分解氨作保護氣氛時,必須保證NH3完全分解,避免殘余的NH3使不銹鋼表面氮化。
使(shi)用(yong)(yong)氫氣(qi)(qi)(qi)或分解氨(an)作保(bao)護氣(qi)(qi)(qi)氛的好處是:可實現釬(han)(han)焊(han)(han)爐的連續工作,便于大批量(liang)(liang)生產;釬(han)(han)焊(han)(han)過(guo)程(cheng)中不需(xu)使(shi)用(yong)(yong)釬(han)(han)劑,且焊(han)(han)后(hou)工件(jian)光亮,無(wu)需(xu)任何焊(han)(han)后(hou)工件(jian)表面清理工作;可配合選用(yong)(yong)的釬(han)(han)料品種多;在批量(liang)(liang)生產條(tiao)件(jian)下焊(han)(han)接成(cheng)本(ben)低(di)。但是使(shi)用(yong)(yong)氫氣(qi)(qi)(qi)或分解氨(an)作保(bao)護氣(qi)(qi)(qi)氛時(shi)要注意(yi)生產安全,當(dang)空(kong)氣(qi)(qi)(qi)中混有4%~74%的氫氣(qi)(qi)(qi)或12.5%~27%氨(an)氣(qi)(qi)(qi)時(shi),會因燃(ran)燒而產生爆炸。
作為惰性(xing)氣(qi)體,氬氣(qi)可(ke)用作爐(lu)中(zhong)釬(han)焊不(bu)銹鋼(gang)時的保(bao)護氣(qi)氛(fen)。與氫氣(qi)和分解(jie)氨不(bu)同(tong),氬氣(qi)不(bu)具有還原性(xing),只是利用其惰性(xing)保(bao)護不(bu)銹鋼(gang)表面(mian)在釬(han)焊過(guo)程中(zhong)不(bu)氧化(hua),所以不(bu)銹鋼(gang)進(jin)爐(lu)釬(han)焊前必須徹底(di)清除其表面(mian)的氧化(hua)膜,并且一(yi)般要求(qiu)氬氣(qi)的露點低于-40℃。
使用氬氣作(zuo)保(bao)護氣氛一般是因(yin)為以下(xia)某種(zhong)(zhong)或多種(zhong)(zhong)原因(yin):①. 可采用含(han)(han)高蒸汽壓元素的釬(han),如錳基釬(han)料(liao)或含(han)(han)錳較(jiao)多的釬(han)料(liao);②. 單件或小(xiao)批量釬(han)焊(han)時(shi),設(she)備成本(ben)低(di);③. 不(bu)銹鋼與(yu)異種(zhong)(zhong)材(cai)(cai)釬(han)焊(han)時(shi)避免某些(xie)材(cai)(cai)料(liao)與(yu)爐內氣氛的反應(ying),如在(zai)含(han)(han)氫氣氛中釬(han)焊(han)連接(jie)不(bu)銹鋼與(yu)鈦合金(jin)時(shi),鈦金(jin)吸氫并(bing)與(yu)氫反應(ying);④. 生產過程安全(quan)。
使用氬氣作保護氣氛時,常見的做法是將真空爐抽至高真空后(10-2~10-3Pa)充入少量氬氣,關閉爐體氣閥后升溫。或者在特制的密封容器內通人流動的氬氣,將空氣趕凈后,容器放入馬弗爐內加熱。也可在趕凈空氣后,關閉氣路,容器放人馬弗爐內加熱,但在升溫過
程中要(yao)隨時(shi)注意容器內的壓(ya)(ya)力(li),當容器內壓(ya)(ya)力(li)超(chao)過(guo)大氣壓(ya)(ya)較多時(shi)應隨時(shi)放出一(yi)(yi)些氣體,以保證(zheng)容器完好(hao)和生(sheng)產(chan)安(an)全。使用(yong)特制的容器還有(you)另一(yi)(yi)個便利(li):當使用(yong)未(wei)經凈化(hua)的普通瓶裝氬氣時(shi),可向釬焊爐(lu)內通入(ru)少許(xu)BF3氣體釬劑(ji),或(huo)加入(ru)少許(xu)氟(fu)(fu)(fu)硼酸鉀(jia)(jia),氟(fu)(fu)(fu)硼酸鉀(jia)(jia)在800~900℃分(fen)解產(chan)生(sheng)BF3.BF3可以去除金屬表(biao)面的氧化(hua)物,促進釬料的潤濕。氣體釬劑(ji)的使用(yong)濃度一(yi)(yi)般控制在0.1%~0.001%(體積分(fen)數),避免焊后形成殘(can)渣(zha)。氟(fu)(fu)(fu)化(hua)物對人體有(you)害,要(yao)注意工作場地(di)的通風。
在真空爐中釬焊不銹鋼是一種常用且理想的方法。釬焊不銹鋼時一般要求真空度達到10-2~10-3Pa,并且要求真空爐的氣體泄漏率小于10-2Pa/s.使用真空爐釬焊不銹鋼的好處是:可避免不銹鋼的氧化;可避免釬焊爐內氣氛對母材的不良影響;真空爐升、降溫速度慢,工件不變形或變形量很小;無論以何種方式添加釬料均不會在接頭內形成氣孔;無需消耗保護氣體;無需氣體凈化裝置;無安全隱患;帶有充氣及快冷風扇置的真空爐同樣具有較高的生產率,并可實現釬焊與焊后工件熱處理的結合。
在氫氣或分解氨氣氛爐中釬焊不銹鋼可使用紫銅、銅基、銀基、錳基、鎳基和金基釬料。在氬氣氛爐中釬焊不銹鋼可使用銅基、銀基、錳基、金基釬料。在真空爐中釬焊不銹鋼可采用紫銅、不含易蒸發元素(Zn、Cd)或僅含少量高蒸汽壓元素(Mn)的銅基和銀基釬料、鎳基釬料和金基釬料。使用鎳基釬料釬焊不銹鋼薄件時,要選擇對母材溶蝕傾向小的釬料。
爐中釬(han)(han)焊(han)(han)(han)時(shi)(shi)(shi)影響釬(han)(han)焊(han)(han)(han)接(jie)頭性(xing)(xing)能(neng),特別是(shi)力學性(xing)(xing)能(neng)的(de)(de)(de)主要工藝參數(shu)包釬(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)、保(bao)溫(wen)(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)(jian)(jian)(jian)。釬(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)一(yi)(yi)般選擇在(zai)(zai)(zai)(zai)(zai)釬(han)(han)料(liao)液相線溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)以(yi)上(shang)50~100℃,保(bao)溫(wen)(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)(jian)(jian)(jian)在(zai)(zai)(zai)(zai)(zai)5~10min.當工件較大(da)時(shi)(shi)(shi),可在(zai)(zai)(zai)(zai)(zai)升溫(wen)(wen)(wen)(wen)(wen)過程中釬(han)(han)料(liao)固相線溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)以(yi)下(xia)某(mou)溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)保(bao)溫(wen)(wen)(wen)(wen)(wen)一(yi)(yi)段(duan)時(shi)(shi)(shi)間(jian)(jian)(jian)(jian)(jian),確(que)保(bao)工件溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)均(jun)勻。使用鎳基釬(han)(han)料(liao)時(shi)(shi)(shi),除了(le)釬(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)和保(bao)溫(wen)(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)(jian)(jian)(jian)外,釬(han)(han)縫(feng)間(jian)(jian)(jian)(jian)(jian)隙也(ye)是(shi)接(jie)頭強(qiang)(qiang)(qiang)度(du)(du)(du)和塑(su)(su)性(xing)(xing)的(de)(de)(de)決定(ding)因素之一(yi)(yi)。圖(tu)3-5、圖(tu)3-6顯示了(le)三種(zhong)鎳基釬(han)(han)料(liao)釬(han)(han)焊(han)(han)(han)不銹(xiu)鋼時(shi)(shi)(shi)釬(han)(han)焊(han)(han)(han)接(jie)頭強(qiang)(qiang)(qiang)度(du)(du)(du)與(yu)釬(han)(han)縫(feng)間(jian)(jian)(jian)(jian)(jian)隙的(de)(de)(de)關系。為降低釬(han)(han)料(liao)的(de)(de)(de)熔(rong)點,鎳基釬(han)(han)料(liao)中含有較多的(de)(de)(de)硼、硅、磷,它(ta)們在(zai)(zai)(zai)(zai)(zai)釬(han)(han)料(liao)組織中以(yi)脆性(xing)(xing)的(de)(de)(de)硼化(hua)物(wu)、硅化(hua)物(wu)、磷化(hua)物(wu)形(xing)式存在(zai)(zai)(zai)(zai)(zai)。釬(han)(han)焊(han)(han)(han)時(shi)(shi)(shi)在(zai)(zai)(zai)(zai)(zai)一(yi)(yi)定(ding)的(de)(de)(de)釬(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)和保(bao)溫(wen)(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)(jian)(jian)(jian)下(xia),當釬(han)(han)縫(feng)間(jian)(jian)(jian)(jian)(jian)隙小(xiao)于某(mou)一(yi)(yi)數(shu)值(zhi)(zhi),硼、硅、磷向母材擴散(san)充分,凝固后釬(han)(han)縫(feng)組織為鎳基固溶體,釬(han)(han)縫(feng)強(qiang)(qiang)(qiang)度(du)(du)(du)高、塑(su)(su)性(xing)(xing)好(hao),此(ci)數(shu)值(zhi)(zhi)稱作該釬(han)(han)料(liao)在(zai)(zai)(zai)(zai)(zai)此(ci)釬(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)(wen)度(du)(du)(du)和保(bao)溫(wen)(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)(jian)(jian)(jian)下(xia)的(de)(de)(de)最大(da)釬(han)(han)焊(han)(han)(han)間(jian)(jian)(jian)(jian)(jian)隙。當釬(han)(han)縫(feng)間(jian)(jian)(jian)(jian)(jian)隙超過最大(da)間(jian)(jian)(jian)(jian)(jian)隙,釬(han)(han)縫(feng)中硼、硅、磷向母材擴散(san)不充分,釬(han)(han)縫(feng)中會存在(zai)(zai)(zai)(zai)(zai)脆性(xing)(xing)化(hua)合(he)物(wu),釬(han)(han)縫(feng)的(de)(de)(de)強(qiang)(qiang)(qiang)度(du)(du)(du)和塑(su)(su)性(xing)(xing)都會下(xia)降。而且在(zai)(zai)(zai)(zai)(zai)一(yi)(yi)定(ding)范圍內,釬(han)(han)縫(feng)越(yue)(yue)寬,釬(han)(han)縫(feng)中脆性(xing)(xing)相越(yue)(yue)多,接(jie)頭的(de)(de)(de)強(qiang)(qiang)(qiang)度(du)(du)(du)和塑(su)(su)性(xing)(xing)越(yue)(yue)低。
在(zai)釬焊(han)實(shi)際部件時,有時部件加工精度(du)或(huo)裝配精度(du)很難(nan)保證釬縫(feng)間(jian)隙(xi)很小,適當(dang)地提高釬焊(han)溫(wen)(wen)(wen)度(du)或(huo)延(yan)長(chang)(chang)保溫(wen)(wen)(wen)時間(jian)可增大最(zui)大釬焊(han)間(jian)隙(xi),見圖(tu)3-7。當(dang)在(zai)高溫(wen)(wen)(wen)下長(chang)(chang)時間(jian)保溫(wen)(wen)(wen)造(zao)成母(mu)材晶粒過(guo)分長(chang)(chang)大或(huo)釬料對母(mu)材溶蝕過(guo)度(du)時,也可在(zai)焊(han)后接(jie)頭冷卻到某一(yi)較(jiao)低溫(wen)(wen)(wen)度(du)保溫(wen)(wen)(wen),通過(guo)擴散(san)消(xiao)除釬縫(feng)中的脆性相而增大最(zui)大釬焊(han)間(jian)隙(xi),見圖(tu)3-8。但由于磷原子較(jiao)大,向母(mu)材中擴散(san)困難(nan),這些措施對Ni-Cr-P和Ni-P這類釬料作(zuo)用(yong)不大。
爐中釬焊時為控制釬料不流到接頭外其他部位或造成工件與卡具的粘連,可在防止釬料潤濕處涂止焊劑。釬焊不銹鋼時可以用TiO2、Y2O3或云母粉與乙醇混和后做止焊劑。