按照氫脆敏感性與應變速率的關系,可以將氫致開裂分為兩大類。


1. 第一(yi)類氫脆


 氫脆的敏感性隨應變速率的增加而增加,即材料加載前內部已存在某種裂紋源,加載后在應力作用下加快了裂紋的形成與擴展。第一類氫脆包括三種形式:①. 氫腐蝕,由于氫在高溫高壓下與金屬中第二相(夾雜物和合金添加物)發生化學反應,生成高壓氣體(如CH4、SiH4)引起材料脫碳、內裂紋和鼓泡的現象;②. 氫鼓泡,過飽和的氫原子在缺陷位置(如夾雜)析出,形成氫分子,在局部造成很高的氫壓,引起表面鼓泡或內部裂紋的現象;③. 氫化物型氫脆,氫與IVB和VB族金屬有較大的親和力,氫含量較高時容易產生脆性的氫化物相,并在隨后受力時成為裂紋源,引起脆斷。


 上述三種(zhong)情(qing)況(kuang)將(jiang)造成金屬永久損(sun)傷,使材料塑性(xing)或強度降低,即使從金屬中除氫損(sun)傷也(ye)不能(neng)消除,塑性(xing)或強度也(ye)不能(neng)恢復,故稱為不可逆氫脆。


2. 第二類氫脆(cui)


 氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)的敏(min)感性(xing)隨應(ying)變速率增加而降(jiang)低,即材(cai)料在(zai)(zai)(zai)(zai)加載前并(bing)不存(cun)在(zai)(zai)(zai)(zai)裂(lie)(lie)紋(wen)源,加載后(hou)在(zai)(zai)(zai)(zai)應(ying)力(li)和(he)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)的交互(hu)(hu)作(zuo)用下(xia)逐漸形(xing)(xing)成(cheng)裂(lie)(lie)紋(wen)源,最(zui)(zui)終導(dao)(dao)致脆(cui)(cui)性(xing)斷(duan)裂(lie)(lie)。第二(er)類(lei)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)包括(kuo)兩(liang)種(zhong)形(xing)(xing)式:一(yi)是(shi)應(ying)力(li)誘(you)發氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)型氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。在(zai)(zai)(zai)(zai)能(neng)夠形(xing)(xing)成(cheng)脆(cui)(cui)性(xing)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)的金屬中(zhong)(zhong),當(dang)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)含(han)量較低或(huo)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)在(zai)(zai)(zai)(zai)固溶體中(zhong)(zhong)的過(guo)(guo)飽和(he)度(du)較低時(shi),尚不能(neng)自(zi)發形(xing)(xing)成(cheng)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)化(hua)物(wu);而在(zai)(zai)(zai)(zai)應(ying)力(li)作(zuo)用下(xia),氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)會向(xiang)應(ying)力(li)集(ji)中(zhong)(zhong)處富(fu)集(ji),當(dang)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)濃度(du)超過(guo)(guo)臨界(jie)值時(shi)就會沉(chen)淀出(chu)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)。這(zhe)種(zhong)應(ying)力(li)誘(you)發的氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)相(xiang)變只在(zai)(zai)(zai)(zai)較低的應(ying)變速率下(xia)出(chu)現,并(bing)由此(ci)導(dao)(dao)致脆(cui)(cui)性(xing)斷(duan)裂(lie)(lie),一(yi)旦(dan)出(chu)現氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)化(hua)物(wu),即使(shi)卸(xie)載除(chu)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing),靜止(zhi)一(yi)段(duan)時(shi)間后(hou)再高速變形(xing)(xing),塑(su)性(xing)也(ye)不能(neng)恢復,故也(ye)是(shi)不可(ke)(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。二(er)是(shi)可(ke)(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。是(shi)指含(han)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)金屬在(zai)(zai)(zai)(zai)高速變形(xing)(xing)時(shi)并(bing)不顯示脆(cui)(cui)性(xing),而在(zai)(zai)(zai)(zai)緩慢變形(xing)(xing)時(shi)由于(yu)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)逐漸向(xiang)應(ying)力(li)集(ji)中(zhong)(zhong)處富(fu)集(ji),在(zai)(zai)(zai)(zai)應(ying)力(li)與氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)交互(hu)(hu)作(zuo)用下(xia)裂(lie)(lie)紋(wen)形(xing)(xing)核(he)、擴展,最(zui)(zui)終導(dao)(dao)致脆(cui)(cui)性(xing)的斷(duan)裂(lie)(lie),在(zai)(zai)(zai)(zai)未(wei)形(xing)(xing)成(cheng)裂(lie)(lie)紋(wen)前去除(chu)載荷,靜置一(yi)段(duan)時(shi)間后(hou)高速變形(xing)(xing),材(cai)料的塑(su)性(xing)可(ke)(ke)以得到恢復,即應(ying)力(li)去除(chu)后(hou)脆(cui)(cui)性(xing)消(xiao)失,因此(ci)稱為可(ke)(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。由內氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)引(yin)起的稱可(ke)(ke)逆內氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui),由外氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)引(yin)起的稱環境氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。通常所說的氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)主(zhu)要指可(ke)(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui),是(shi)氫(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)(qing)致開(kai)裂(lie)(lie)中(zhong)(zhong)最(zui)(zui)主(zhu)要、最(zui)(zui)危險的破壞形(xing)(xing)式。