按照氫脆敏感性與應變速率的關系,可以將氫致開裂分為兩大類。
1. 第一類氫(qing)脆
氫脆的敏感性隨應變速率的增加而增加,即材料加載前內部已存在某種裂紋源,加載后在應力作用下加快了裂紋的形成與擴展。第一類氫脆包括三種形式:①. 氫腐蝕,由于氫在高溫高壓下與金屬中第二相(夾雜物和合金添加物)發生化學反應,生成高壓氣體(如CH4、SiH4)引起材料脫碳、內裂紋和鼓泡的現象;②. 氫鼓泡,過飽和的氫原子在缺陷位置(如夾雜)析出,形成氫分子,在局部造成很高的氫壓,引起表面鼓泡或內部裂紋的現象;③. 氫化物型氫脆,氫與IVB和VB族金屬有較大的親和力,氫含量較高時容易產生脆性的氫化物相,并在隨后受力時成為裂紋源,引起脆斷。
上(shang)述三(san)種情況將造成金屬(shu)(shu)永久損(sun)傷,使材料塑性或強度降低,即使從金屬(shu)(shu)中除氫(qing)損(sun)傷也不能(neng)消除,塑性或強度也不能(neng)恢復,故稱為不可(ke)逆氫(qing)脆。
2. 第二類氫脆(cui)
氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)的(de)(de)(de)敏感性(xing)(xing)隨應(ying)(ying)(ying)(ying)變(bian)速(su)率增加而降(jiang)低(di)(di)(di),即材(cai)(cai)料(liao)(liao)在(zai)(zai)加載(zai)(zai)前并不(bu)(bu)存在(zai)(zai)裂(lie)(lie)(lie)紋(wen)源,加載(zai)(zai)后在(zai)(zai)應(ying)(ying)(ying)(ying)力(li)(li)和(he)氫(qing)(qing)(qing)(qing)(qing)的(de)(de)(de)交(jiao)互(hu)作用下(xia)逐漸(jian)形(xing)(xing)(xing)(xing)成裂(lie)(lie)(lie)紋(wen)源,最(zui)終導(dao)致脆(cui)(cui)(cui)(cui)(cui)性(xing)(xing)斷(duan)裂(lie)(lie)(lie)。第二類氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)包括兩(liang)種(zhong)形(xing)(xing)(xing)(xing)式(shi):一是(shi)(shi)應(ying)(ying)(ying)(ying)力(li)(li)誘發氫(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)(wu)型氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)。在(zai)(zai)能夠形(xing)(xing)(xing)(xing)成脆(cui)(cui)(cui)(cui)(cui)性(xing)(xing)氫(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)(wu)的(de)(de)(de)金屬中(zhong),當氫(qing)(qing)(qing)(qing)(qing)含量較(jiao)低(di)(di)(di)或氫(qing)(qing)(qing)(qing)(qing)在(zai)(zai)固溶體(ti)中(zhong)的(de)(de)(de)過(guo)飽和(he)度較(jiao)低(di)(di)(di)時(shi),尚不(bu)(bu)能自發形(xing)(xing)(xing)(xing)成氫(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)(wu);而在(zai)(zai)應(ying)(ying)(ying)(ying)力(li)(li)作用下(xia),氫(qing)(qing)(qing)(qing)(qing)會向應(ying)(ying)(ying)(ying)力(li)(li)集(ji)(ji)中(zhong)處富集(ji)(ji),當氫(qing)(qing)(qing)(qing)(qing)濃(nong)度超(chao)過(guo)臨界(jie)值(zhi)時(shi)就會沉淀出氫(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)(wu)。這種(zhong)應(ying)(ying)(ying)(ying)力(li)(li)誘發的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)(wu)相變(bian)只在(zai)(zai)較(jiao)低(di)(di)(di)的(de)(de)(de)應(ying)(ying)(ying)(ying)變(bian)速(su)率下(xia)出現,并由此導(dao)致脆(cui)(cui)(cui)(cui)(cui)性(xing)(xing)斷(duan)裂(lie)(lie)(lie),一旦(dan)出現氫(qing)(qing)(qing)(qing)(qing)化(hua)物(wu)(wu),即使卸載(zai)(zai)除氫(qing)(qing)(qing)(qing)(qing),靜(jing)止(zhi)一段時(shi)間(jian)(jian)后再(zai)高(gao)速(su)變(bian)形(xing)(xing)(xing)(xing),塑性(xing)(xing)也(ye)不(bu)(bu)能恢(hui)復(fu),故也(ye)是(shi)(shi)不(bu)(bu)可(ke)逆(ni)氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)。二是(shi)(shi)可(ke)逆(ni)氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)。是(shi)(shi)指含氫(qing)(qing)(qing)(qing)(qing)金屬在(zai)(zai)高(gao)速(su)變(bian)形(xing)(xing)(xing)(xing)時(shi)并不(bu)(bu)顯(xian)示(shi)脆(cui)(cui)(cui)(cui)(cui)性(xing)(xing),而在(zai)(zai)緩慢變(bian)形(xing)(xing)(xing)(xing)時(shi)由于氫(qing)(qing)(qing)(qing)(qing)逐漸(jian)向應(ying)(ying)(ying)(ying)力(li)(li)集(ji)(ji)中(zhong)處富集(ji)(ji),在(zai)(zai)應(ying)(ying)(ying)(ying)力(li)(li)與氫(qing)(qing)(qing)(qing)(qing)交(jiao)互(hu)作用下(xia)裂(lie)(lie)(lie)紋(wen)形(xing)(xing)(xing)(xing)核、擴展(zhan),最(zui)終導(dao)致脆(cui)(cui)(cui)(cui)(cui)性(xing)(xing)的(de)(de)(de)斷(duan)裂(lie)(lie)(lie),在(zai)(zai)未形(xing)(xing)(xing)(xing)成裂(lie)(lie)(lie)紋(wen)前去除載(zai)(zai)荷,靜(jing)置一段時(shi)間(jian)(jian)后高(gao)速(su)變(bian)形(xing)(xing)(xing)(xing),材(cai)(cai)料(liao)(liao)的(de)(de)(de)塑性(xing)(xing)可(ke)以得到恢(hui)復(fu),即應(ying)(ying)(ying)(ying)力(li)(li)去除后脆(cui)(cui)(cui)(cui)(cui)性(xing)(xing)消失,因此稱為可(ke)逆(ni)氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)。由內(nei)氫(qing)(qing)(qing)(qing)(qing)引起(qi)的(de)(de)(de)稱可(ke)逆(ni)內(nei)氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui),由外氫(qing)(qing)(qing)(qing)(qing)引起(qi)的(de)(de)(de)稱環境氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)。通(tong)常所說的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui)主(zhu)要(yao)指可(ke)逆(ni)氫(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)(cui),是(shi)(shi)氫(qing)(qing)(qing)(qing)(qing)致開裂(lie)(lie)(lie)中(zhong)最(zui)主(zhu)要(yao)、最(zui)危險的(de)(de)(de)破壞形(xing)(xing)(xing)(xing)式(shi)。

