按照氫脆敏感性與應變速率的關系,可以將氫致開裂分為兩大類。


1. 第(di)一類(lei)氫脆


 氫脆的敏感性隨應變速率的增加而增加,即材料加載前內部已存在某種裂紋源,加載后在應力作用下加快了裂紋的形成與擴展。第一類氫脆包括三種形式:①. 氫腐蝕,由于氫在高溫高壓下與金屬中第二相(夾雜物和合金添加物)發生化學反應,生成高壓氣體(如CH4、SiH4)引起材料脫碳、內裂紋和鼓泡的現象;②. 氫鼓泡,過飽和的氫原子在缺陷位置(如夾雜)析出,形成氫分子,在局部造成很高的氫壓,引起表面鼓泡或內部裂紋的現象;③. 氫化物型氫脆,氫與IVB和VB族金屬有較大的親和力,氫含量較高時容易產生脆性的氫化物相,并在隨后受力時成為裂紋源,引起脆斷。


 上述三(san)種(zhong)情(qing)況將造成金屬永久(jiu)損(sun)傷,使材料塑(su)性或(huo)強度降低,即使從金屬中除氫(qing)損(sun)傷也不能(neng)消除,塑(su)性或(huo)強度也不能(neng)恢復,故稱為不可逆氫(qing)脆(cui)。


2. 第二類氫脆(cui)


 氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)的(de)(de)(de)敏感性(xing)隨(sui)應(ying)(ying)變(bian)速(su)率增加(jia)(jia)而降低(di),即材料在(zai)(zai)加(jia)(jia)載前并不(bu)(bu)存在(zai)(zai)裂(lie)(lie)紋(wen)(wen)(wen)源(yuan),加(jia)(jia)載后在(zai)(zai)應(ying)(ying)力(li)(li)(li)和氫(qing)(qing)(qing)(qing)(qing)(qing)的(de)(de)(de)交互作(zuo)用(yong)下逐(zhu)漸形(xing)(xing)(xing)(xing)(xing)成(cheng)裂(lie)(lie)紋(wen)(wen)(wen)源(yuan),最(zui)(zui)終(zhong)導致(zhi)(zhi)脆(cui)(cui)性(xing)斷裂(lie)(lie)。第二類(lei)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)包括兩種形(xing)(xing)(xing)(xing)(xing)式(shi):一(yi)是(shi)(shi)應(ying)(ying)力(li)(li)(li)誘(you)發(fa)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物型氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。在(zai)(zai)能夠形(xing)(xing)(xing)(xing)(xing)成(cheng)脆(cui)(cui)性(xing)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物的(de)(de)(de)金屬中,當(dang)氫(qing)(qing)(qing)(qing)(qing)(qing)含(han)量較低(di)或氫(qing)(qing)(qing)(qing)(qing)(qing)在(zai)(zai)固溶體中的(de)(de)(de)過飽和度較低(di)時(shi)(shi),尚不(bu)(bu)能自發(fa)形(xing)(xing)(xing)(xing)(xing)成(cheng)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物;而在(zai)(zai)應(ying)(ying)力(li)(li)(li)作(zuo)用(yong)下,氫(qing)(qing)(qing)(qing)(qing)(qing)會(hui)向(xiang)應(ying)(ying)力(li)(li)(li)集(ji)中處富集(ji),當(dang)氫(qing)(qing)(qing)(qing)(qing)(qing)濃(nong)度超過臨界值時(shi)(shi)就(jiu)會(hui)沉淀出氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物。這(zhe)種應(ying)(ying)力(li)(li)(li)誘(you)發(fa)的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物相變(bian)只在(zai)(zai)較低(di)的(de)(de)(de)應(ying)(ying)變(bian)速(su)率下出現,并由(you)此導致(zhi)(zhi)脆(cui)(cui)性(xing)斷裂(lie)(lie),一(yi)旦出現氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物,即使卸載除(chu)氫(qing)(qing)(qing)(qing)(qing)(qing),靜(jing)止一(yi)段(duan)時(shi)(shi)間(jian)后再高(gao)速(su)變(bian)形(xing)(xing)(xing)(xing)(xing),塑性(xing)也(ye)不(bu)(bu)能恢復,故也(ye)是(shi)(shi)不(bu)(bu)可(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。二是(shi)(shi)可(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。是(shi)(shi)指含(han)氫(qing)(qing)(qing)(qing)(qing)(qing)金屬在(zai)(zai)高(gao)速(su)變(bian)形(xing)(xing)(xing)(xing)(xing)時(shi)(shi)并不(bu)(bu)顯示脆(cui)(cui)性(xing),而在(zai)(zai)緩慢變(bian)形(xing)(xing)(xing)(xing)(xing)時(shi)(shi)由(you)于氫(qing)(qing)(qing)(qing)(qing)(qing)逐(zhu)漸向(xiang)應(ying)(ying)力(li)(li)(li)集(ji)中處富集(ji),在(zai)(zai)應(ying)(ying)力(li)(li)(li)與氫(qing)(qing)(qing)(qing)(qing)(qing)交互作(zuo)用(yong)下裂(lie)(lie)紋(wen)(wen)(wen)形(xing)(xing)(xing)(xing)(xing)核、擴(kuo)展,最(zui)(zui)終(zhong)導致(zhi)(zhi)脆(cui)(cui)性(xing)的(de)(de)(de)斷裂(lie)(lie),在(zai)(zai)未形(xing)(xing)(xing)(xing)(xing)成(cheng)裂(lie)(lie)紋(wen)(wen)(wen)前去(qu)除(chu)載荷,靜(jing)置一(yi)段(duan)時(shi)(shi)間(jian)后高(gao)速(su)變(bian)形(xing)(xing)(xing)(xing)(xing),材料的(de)(de)(de)塑性(xing)可(ke)以(yi)得到恢復,即應(ying)(ying)力(li)(li)(li)去(qu)除(chu)后脆(cui)(cui)性(xing)消(xiao)失,因此稱為可(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。由(you)內(nei)氫(qing)(qing)(qing)(qing)(qing)(qing)引起的(de)(de)(de)稱可(ke)逆內(nei)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui),由(you)外氫(qing)(qing)(qing)(qing)(qing)(qing)引起的(de)(de)(de)稱環(huan)境氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)。通(tong)常所(suo)說(shuo)的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)主(zhu)要(yao)指可(ke)逆氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui),是(shi)(shi)氫(qing)(qing)(qing)(qing)(qing)(qing)致(zhi)(zhi)開裂(lie)(lie)中最(zui)(zui)主(zhu)要(yao)、最(zui)(zui)危險的(de)(de)(de)破壞形(xing)(xing)(xing)(xing)(xing)式(shi)。