一塊金(jin)屬(shu),表面看(kan)來挺光滑(hua),可(ke)是在顯微鏡下就會發現,它的(de)結構很不均勻(yun),這(zhe)就為“病(bing)從口入(ru)”大開了方(fang)便之門,因(yin)為金(jin)屬(shu)遍體都是“口”,準確(que)一點說,不是病(bing)從口入(ru),而(er)是病(bing)從“皮(pi)”入(ru)了。所以(yi)金(jin)屬(shu)的(de)常見病(bing)--腐蝕,一般都開始于“皮(pi)膚病(bing)”。首先是金(jin)屬(shu)“皮(pi)膚潰瘍”,然后逐漸侵入(ru)到內部。由于金(jin)屬(shu)接觸(chu)的(de)物(wu)質(zhi)多種(zhong)多樣,“得病(bing)”的(de)條件也各(ge)不相同,所以(yi)金(jin)屬(shu)的(de)常見病(bing)還可(ke)以(yi)分為許多種(zhong)。也就是說,金(jin)屬(shu)腐蝕可(ke)以(yi)分為許多種(zhong)類。
金(jin)屬腐(fu)蝕分類的(de)(de)方(fang)法很多(duo),常見的(de)(de)一種就是(shi)(shi)根據(ju)腐(fu)蝕過程中是(shi)(shi)否有(you)電(dian)(dian)流產生(sheng),分為化學(xue)(xue)腐(fu)蝕和(he)電(dian)(dian)化學(xue)(xue)腐(fu)蝕兩類。化學(xue)(xue)腐(fu)蝕一般是(shi)(shi)在干燥和(he)高溫的(de)(de)環(huan)境下發(fa)生(sheng)的(de)(de),它是(shi)(shi)金(jin)屬的(de)(de)“干熱病(bing)(bing)”;電(dian)(dian)化學(xue)(xue)腐(fu)蝕是(shi)(shi)在潮濕的(de)(de)環(huan)境下發(fa)生(sheng)的(de)(de),它是(shi)(shi)金(jin)屬的(de)(de)“風(feng)濕病(bing)(bing)”。
化學(xue)腐(fu)(fu)蝕(shi)是(shi)金(jin)(jin)屬(shu)在(zai)不導電環境中的(de)腐(fu)(fu)蝕(shi),它是(shi)金(jin)(jin)屬(shu)與某種物(wu)質直(zhi)接(jie)接(jie)觸(chu)(chu)時(shi)發(fa)(fa)生(sheng)的(de)化學(xue)反(fan)應(ying)。在(zai)化學(xue)腐(fu)(fu)蝕(shi)中,和金(jin)(jin)屬(shu)接(jie)觸(chu)(chu)發(fa)(fa)生(sheng)反(fan)應(ying)的(de)物(wu)質可以(yi)是(shi)氣體(ti),也(ye)可以(yi)是(shi)液體(ti),所(suo)以(yi)化學(xue)腐(fu)(fu)蝕(shi)又分為氣體(ti)腐(fu)(fu)蝕(shi)和液體(ti)腐(fu)(fu)蝕(shi)兩種。
在高溫下,或(huo)周(zhou)圍沒有(you)導電物質的(de)(de)條件下,金(jin)屬與(yu)空氣(qi)或(huo)其(qi)他(ta)其(qi)他(ta)發(fa)(fa)生(sheng)(sheng)反(fan)(fan)應(ying)(ying),表面生(sheng)(sheng)成氧(yang)(yang)化(hua)(hua)物或(huo)其(qi)他(ta)化(hua)(hua)合物的(de)(de)現象(xiang),稱為氣(qi)體腐(fu)(fu)蝕。自(zi)然(ran)界中(zhong),氣(qi)體腐(fu)(fu)蝕的(de)(de)現象(xiang)也(ye)是(shi)很多。例如,鐵在空氣(qi)中(zhong)或(huo)氧(yang)(yang)氣(qi)中(zhong)加熱時,表面會生(sheng)(sheng)成鐵的(de)(de)氧(yang)(yang)化(hua)(hua)物膜;鋁在空氣(qi)中(zhong)會與(yu)氧(yang)(yang)氣(qi)反(fan)(fan)應(ying)(ying),表面生(sheng)(sheng)成一層氧(yang)(yang)化(hua)(hua)鋁薄膜。像(xiang)這樣(yang),金(jin)屬與(yu)周(zhou)圍的(de)(de)物質接觸發(fa)(fa)生(sheng)(sheng)反(fan)(fan)應(ying)(ying)生(sheng)(sheng)成了化(hua)(hua)合物,我們就(jiu)說金(jin)屬被腐(fu)(fu)蝕了,生(sheng)(sheng)成的(de)(de)化(hua)(hua)合物(膜)就(jiu)是(shi)腐(fu)(fu)蝕的(de)(de)產物(常(chang)稱作銹(xiu))。
金(jin)屬在(zai)(zai)不(bu)導電的(de)(de)(de)(de)液(ye)(ye)(ye)(ye)體(ti)里的(de)(de)(de)(de)腐(fu)(fu)蝕也是一(yi)種化(hua)(hua)學(xue)腐(fu)(fu)蝕,叫做液(ye)(ye)(ye)(ye)體(ti)腐(fu)(fu)蝕。銀(yin)可與(yu)(yu)(yu)碘(dian)發生液(ye)(ye)(ye)(ye)體(ti)腐(fu)(fu)蝕。例如把碘(dian)溶(rong)解(jie)于(yu)乙(yi)醚中(zhong)(zhong),制(zhi)成(cheng)碘(dian)的(de)(de)(de)(de)乙(yi)醚溶(rong)液(ye)(ye)(ye)(ye)。乙(yi)醚是一(yi)種有(you)(you)機(ji)物(wu),不(bu)能導電。把銀(yin)塊投入溶(rong)液(ye)(ye)(ye)(ye)中(zhong)(zhong),溶(rong)解(jie)了的(de)(de)(de)(de)碘(dian)能夠與(yu)(yu)(yu)銀(yin)反(fan)(fan)應(ying),在(zai)(zai)銀(yin)的(de)(de)(de)(de)表(biao)面生產(chan)碘(dian)化(hua)(hua)銀(yin)膜。石油(you)中(zhong)(zhong)往(wang)往(wang)含有(you)(you)硫(liu)、硫(liu)化(hua)(hua)氫(qing)及某些含硫(liu)的(de)(de)(de)(de)有(you)(you)機(ji)物(wu),石油(you)中(zhong)(zhong)還含有(you)(you)少量(liang)水(shui)(shui),這(zhe)少量(liang)的(de)(de)(de)(de)水(shui)(shui)一(yi)般(ban)不(bu)能與(yu)(yu)(yu)硫(liu)的(de)(de)(de)(de)化(hua)(hua)合物(wu)形成(cheng)導電溶(rong)液(ye)(ye)(ye)(ye),但它卻能加(jia)速硫(liu)的(de)(de)(de)(de)化(hua)(hua)合物(wu)與(yu)(yu)(yu)金(jin)屬發生化(hua)(hua)學(xue)反(fan)(fan)應(ying),成(cheng)為反(fan)(fan)應(ying)的(de)(de)(de)(de)催(cui)化(hua)(hua)劑。例如,硫(liu)化(hua)(hua)氫(qing)可與(yu)(yu)(yu)鐵、鉛(qian)、銅(tong)、汞、銀(yin)等反(fan)(fan)應(ying),生成(cheng)這(zhe)些金(jin)屬的(de)(de)(de)(de)硫(liu)化(hua)(hua)物(wu),單質硫(liu)也可與(yu)(yu)(yu)銅(tong)、汞、銀(yin)等金(jin)屬反(fan)(fan)應(ying),所以儲存石油(you)的(de)(de)(de)(de)容器上部或蓋子往(wang)往(wang)被(bei)硫(liu)化(hua)(hua)氫(qing)腐(fu)(fu)蝕。在(zai)(zai)煉油(you)廠,常采用耐硫(liu)化(hua)(hua)氫(qing)腐(fu)(fu)蝕的(de)(de)(de)(de)鋁箔(bo)來保護這(zhe)些容器。
化學(xue)(xue)腐蝕比較簡單(dan),而且只(zhi)在(zai)某些特定條件(jian)下才(cai)會(hui)發生(sheng)。在(zai)生(sheng)產和(he)日(ri)常生(sheng)活中普遍存在(zai)的、破壞最嚴重的是電化學(xue)(xue)腐蝕,它是金(jin)屬常患(huan)的“風濕(shi)病”。
電(dian)(dian)(dian)(dian)(dian)化(hua)腐(fu)蝕是(shi)指金屬(shu)(shu)與電(dian)(dian)(dian)(dian)(dian)解質溶(rong)(rong)液作(zuo)用所發(fa)生(sheng)(sheng)的(de)(de)(de)腐(fu)蝕。它(ta)的(de)(de)(de)特點是(shi)在腐(fu)蝕過程中(zhong)有(you)電(dian)(dian)(dian)(dian)(dian)流產(chan)生(sheng)(sheng),這是(shi)金屬(shu)(shu)表面發(fa)生(sheng)(sheng)腐(fu)蝕電(dian)(dian)(dian)(dian)(dian)池作(zuo)用的(de)(de)(de)結果。通常在電(dian)(dian)(dian)(dian)(dian)化(hua)腐(fu)蝕中(zhong)規(gui)定,電(dian)(dian)(dian)(dian)(dian)極(ji)電(dian)(dian)(dian)(dian)(dian)位(wei)較(jiao)低(di)的(de)(de)(de)金屬(shu)(shu)為(wei)(wei)(wei)陽(yang)極(ji),電(dian)(dian)(dian)(dian)(dian)極(ji)電(dian)(dian)(dian)(dian)(dian)位(wei)較(jiao)高的(de)(de)(de)金屬(shu)(shu)為(wei)(wei)(wei)陰(yin)極(ji)。當兩種電(dian)(dian)(dian)(dian)(dian)極(ji)電(dian)(dian)(dian)(dian)(dian)位(wei)不同(tong)的(de)(de)(de)金屬(shu)(shu)相接觸,或(huo)(huo)同(tong)種金屬(shu)(shu)的(de)(de)(de)不同(tong)的(de)(de)(de)部位(wei)具有(you)不同(tong)電(dian)(dian)(dian)(dian)(dian)極(ji)電(dian)(dian)(dian)(dian)(dian)位(wei)時,它(ta)們侵(qin)入電(dian)(dian)(dian)(dian)(dian)解質溶(rong)(rong)液(潮濕氣體、海水、酸、堿、鹽的(de)(de)(de)水溶(rong)(rong)液或(huo)(huo)土壤等)后會(hui)變形成(cheng)腐(fu)蝕電(dian)(dian)(dian)(dian)(dian)池。結果,作(zuo)為(wei)(wei)(wei)陽(yang)極(ji)的(de)(de)(de)(電(dian)(dian)(dian)(dian)(dian)極(ji)電(dian)(dian)(dian)(dian)(dian)位(wei)低(di)的(de)(de)(de))金屬(shu)(shu),由于(yu)不斷失去電(dian)(dian)(dian)(dian)(dian)子并(bing)將自己的(de)(de)(de)離子投入溶(rong)(rong)液而被腐(fu)蝕,而作(zuo)為(wei)(wei)(wei)陰(yin)極(ji)的(de)(de)(de)(電(dian)(dian)(dian)(dian)(dian)極(ji)電(dian)(dian)(dian)(dian)(dian)位(wei)高的(de)(de)(de))金屬(shu)(shu)由于(yu)僅起(qi)著傳遞(di)電(dian)(dian)(dian)(dian)(dian)子的(de)(de)(de)作(zuo)用,本身沒有(you)發(fa)生(sheng)(sheng)腐(fu)蝕及其他變化(hua)。