21世紀原(yuan)(yuan)油(you)(you)重(zhong)(zhong)質(zhi)化(hua)(hua)(hua)和(he)劣質(zhi)化(hua)(hua)(hua)的(de)(de)趨勢將(jiang)越(yue)來(lai)越(yue)明(ming)顯,我國(guo)煉(lian)油(you)(you)行業(ye)加工(gong)(gong)含(han)硫原(yuan)(yuan)油(you)(you)和(he)重(zhong)(zhong)質(zhi)原(yuan)(yuan)油(you)(you)的(de)(de)比(bi)例將(jiang)越(yue)來(lai)越(yue)大。在(zai)煉(lian)油(you)(you)廠含(han)硫重(zhong)(zhong)質(zhi)原(yuan)(yuan)油(you)(you)加工(gong)(gong)工(gong)(gong)藝(yi)流程(cheng)的(de)(de)選(xuan)擇(ze)和(he)配置上,可(ke)采(cai)用延遲焦化(hua)(hua)(hua)、渣(zha)油(you)(you)加氫、重(zhong)(zhong)油(you)(you)催(cui)化(hua)(hua)(hua)裂化(hua)(hua)(hua)(RFCC)或相應(ying)的(de)(de)組(zu)合(he)工(gong)(gong)藝(yi);對于產品(pin)(pin)精(jing)制(zhi)則普遍采(cai)用加氫精(jing)制(zhi)工(gong)(gong)藝(yi),以(yi)滿(man)足日(ri)益提(ti)高的(de)(de)環(huan)保和(he)產品(pin)(pin)質(zhi)量(liang)的(de)(de)要求(qiu)。因此,在(zai)煉(lian)油(you)(you)廠總的(de)(de)加工(gong)(gong)流程(cheng)中(zhong),各種臨氫工(gong)(gong)藝(yi)已(yi)日(ri)益成為煉(lian)油(you)(you)廠主要的(de)(de)加工(gong)(gong)手(shou)段(duan)。
工業上生產氫氣(qi)(qi)(qi)的方法(fa)(fa)有很多,如(ru)煤或焦炭的水(shui)煤氣(qi)(qi)(qi)法(fa)(fa)、渣(zha)油或重(zhong)油的部分(fen)氧化(hua)法(fa)(fa)、輕(qing)烴水(shui)蒸(zheng)(zheng)氣(qi)(qi)(qi)轉化(hua)法(fa)(fa)、煉油廠(chang)富(fu)氫氣(qi)(qi)(qi)體(ti)(ti)凈(jing)化(hua)分(fen)離(li)法(fa)(fa)、甲醇為(wei)原料蒸(zheng)(zheng)汽(qi)重(zhong)整法(fa)(fa)以及電解水(shui)法(fa)(fa)等(deng)。而(er)輕(qing)烴水(shui)蒸(zheng)(zheng)氣(qi)(qi)(qi)轉化(hua)法(fa)(fa)以其(qi)工藝(yi)成熟可靠、投資低廉、操作(zuo)方便而(er)占主(zhu)導(dao)地位(wei)。就(jiu)全球(qiu)范圍(wei)而(er)言(yan),對于煉油企業,除(chu)從含氫氣(qi)(qi)(qi)體(ti)(ti)中回收氫外(wai),目前大約90%的制氫裝(zhuang)置都(dou)采用烴類(lei)水(shui)蒸(zheng)(zheng)氣(qi)(qi)(qi)轉化(hua)法(fa)(fa)。
常規脫碳法制氫裝置典型工藝流程,如(ru)圖5-143所示(shi)。